物质安全资料表Material Safety Data Sheet一 制造商或供应商资料(Manufacturer Information)
公司名称Company Name 地址Address联络人Person in charge紧急联络电话Emergency Phone #物质名称Item Name合金成分Alloy Composition传真号码Fax#无铅高温锡条 Lead Free Solder barSn-Cu0.7二 危害物质分类(Hazardous Ingredients)
危害性成份Hazardous components名称化学式比率weight%Common NameChemical Formul短时间时量化学文摘社时量平均容最高容许浓测试动物平均容许浓测试动物吸收途径登记号码许浓度度吸收途径度CAS.NOTWA(mg/m3)STEL(mg/m3)CEILINGLD 50LC 50锡Tin铜CopperSnCu99.3±0.50.7±0.17440-31-57440-50-82242N/AN/AN/AN/AN/AN/A三 危害物质定义(Hazards Identification)
物质状态及外观Physical State and Appearance警急情况概要 Emergency Overview癌症的风险取决于暴露的时间长短及程度避免眼睛,皮肤,以及衣物的接触,不要吞食SIGMA
固体Solid警告!Warning!Risk of cancer depends on duration and level of exposure . Avoid contact with eyes, skin and clothing . DO NOT ingest…Solder Bar….
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避免吸入粉尘,避免过长或是反复的皮肤接触保持容器紧闭,使用适当的通风设备怀孕期间避免暴露,并于使用后彻底洗净Avoid breathing dust. Avoid prolinged or repeatedcontact withskin .Keep container closed. Use only with adequate ventilationAvoid exposuer during pergnancy. Wash thoroughly after handling. 潜入人体的途径Routes of Entry吸入，吞食Inhalation,Ingestion.潜在的急性健康影响 Potential Acute Health Effects眼睛Eyes皮肤Skin如果发生眼睛接触（刺激物），这产品可能是有害的.This product may be hazardous in caseof eye contact (imitant)如果发生皮肤接触(刺激物，致敏物质），这产品可能是有害的.皮肤发炎的症状特微有发痒，鳞癣，发红，或偶尔会起水泡.This product may be hazardous in case of skin contact (imitant,senSkin inflammation is characterized by itching,scaling,reddening,oroccasionally,blistering.吸入Inhalation 如果发生吸入的情况，这个产品所产生的烟尘可能是有害的.Fumes and/ or dusts produced by this product may be hazardous ininhalation.如果发生吞食的情况，这个产品可能是有害的.This product may be hazardous in case of ingestion.Potential Chronic Health Effects慢性病影响：如果发生吸入或是吞食的情况；这个产品所产生的烟尘可能是有害的.如果发生皮肤接触品所产生的烟尘可能是有害的.如果发生皮肤接触（刺激物，致敏物质），或是眼睛接触（刺激物），这产品可能是有害的.对皮肤非腐蚀性，非渗透性.Chronic effects:fumes and/ or dusts produced by this product mayin case of ingestion,of inhalation. This product may be hazardousiskin contact(irritant, sensitizer),of eye contact (irritant).Non-corrosfor skin.Non-permeator by skibn.吞食Ingestion潜在的慢性健康影响暴露过度所造成的重大医学疾病Medical Conditions Aggravated by overexposure.暴露过度 症候 徵状详见毒物资料（第十一点说明）重复或是过长的暴露对于重大医学疾病上尚未发生过Repeated or prolonged exposure is not known to aggravate medical condition.无法提供Not availabieSee Toxicological Information (Section1四 急救措施（First Aid Measrues)
眼睛接触Eye Contact检查并移动任何隐形眼镜.如果发生任何接触,马上用大量清水冲洗至15分钟.立即就医.Check for and remove any contact lenses.In case ofcontact,immediately flush eyes with plenty of water for at least 15 minutes.Get medical attention.皮肤接触 Skin Contact在皮肤接触后,马上用大量清水及非磨砂皂清洗,假如持续过敏,马上就医. After contact with skin,wash immediately with plenty用消毒肥皂清洗，并用抗菌药膏覆盖于受污染的皮肤上，马…Solder Bar….Page 2/8有害物质的皮肤接触SIGMAHazardous Skin Contact Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterialcream contaminated skin with an ante-becterial cream.Seek medical attention.吸入 Inhalation如果吸入，移至新鲜空气处，如果不能呼吸，施予人工呼吸.假如呼吸困难，给予氧气，马上就医If inhaled,remove to fresh air.if not breathing, give artificial resIF breathing is difficult ,give oxygen.Get medical attention.有害物质的吸入 Hazardous Inhalation 无法提供 Not available.吞食Ingestion不可催吐，除非经医疗人员指导，千万不可给意识不清者吞食任何物品。假如有此类物质大量吞食，马上就医，松开紧贴的衣物，如如衣领，领带，皮带或腰带等。Do NOT induce vomiting unless directed to do so by medical personnel.Never give anything by mouth to an unconsicous person.If large quantitiesof this material are swallowed,call a physician immediately.Loosen tightclothing such as a collar,tie ,belt or waistband.五 火警的措施（Fire Fighting Measures)
产品的易燃性 Flammability of the product 自然温度Auto-lgnition Temperature 闪火点Flash Points易燃的极限Flammable Limits产品的燃烧 Products of Combustion 呈现于各种物质一的火灾危害Explosion Hazards in Presence of Various Substances 不易燃Non-flammable.不适用Not applicable.不适用Not applicable.不适用Not applicable.无法提供 Not available.在开放性的火焰下为可燃、氧化物质，金属，酸的情形下是不可燃的。Combustible in presence of open flames.Non-flammable inpresence of shocks,of oxidizing materials,of metals,of acids,of allkalis,of moisture.呈现于各种物质一的火灾危害Explosion Hazards in Presence of Various Substances 静态物质排出的爆炸现像：无法提供。撞击及热不会有爆炸的情形发生。Risk of explosion of the product in presence of staticdischarge:Not available.Non-explosive in presence of shocks,of heat.小火：使用乾粉灭火器大火：使用水灭火SMALL FIRE:Use DRY Chemical powderLARGE FIRE : USE water不适用Not applicable.大量的金属是不易燃的，助焊剂蕊直接触火焰会燃烧。粉尘与粉末可能是易燃的。Massive metal is nonflammable.Flux core will burn on contactwith direct flame.Dust and powders may be flammable.无法提供 Not available.火警的媒介与指示Fire Fighting Media and Instructions防火衣 Protective Clothing(Fire)火灾危害的特殊注解Special Remarks on Fire Hazards爆炸危害的特殊注解Special Remarks on Explosion Hazards六 避免意外的措施(Accidental release measures)
小量的溢出和泄漏SIGMA
融熔中的金属：再拿起前及回到过程是回收前，请待其冷却。…Solder Bar….
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Small Spill and Leak 其他：使用适当的工具溢出的回体转入一个保存的容器。MOLTEN METAL:Let cool before picking up and returning to processor recycling.OTHER:Use apropriate tools to put the spilled solidin a container reserved to that effect.大量的溢出和泄漏Large Spill and Leak 融熔中的金属：再拿起前及回到过程是回收前，请待其冷却。其他：使用适当的工具溢出的回体转入一个保存的容器。MOLTEN METAL:Let cool before picking up and returning to processor recycling.OTHER:Use apropriate tools to put the spilled solidin a container reserved to that effect.七 操作与储藏(Handing and storage)
操作 Handling穿戴适当的保护衣物，在通风良好的区域操作，使用时请勿进食，饮水或是抽烟。避免接触到皮肤及眼睛，并于使用后，用水及香皂徹底洗手。Wear suitable protective clothing.Use in a well wentilated area.When using do not eat ,dring or smoke .Avoid contact with skin and eyes.After handing,always wash hands thoroughly with soap and water.储藏Storage 保持紧密闭合，保持容器在一个凉爽，通风良好的地区。Keep container tightly closed.Keep container in a cool ,well-ventilated area.八 暴露的控制，个人的保护措施(Exposure Controls,Personal Protection)
工程上的保护Engineering Protection使用围住制程区域：区域排气通风良好，或其他工程上控制来维持空气中的水平在建议爆炸范围之下。假如使用者操作过程制造出烟，尘或雾，使用通风良好的设备维护空气中污染的爆炸性，低于爆炸界线。Use process enclosures,local exhaust ventilation,or other engineeringcontrols to keep airbome contaminants below the exposure limit.个人安全的保护Personal Protection眼睛Eyes操作时：安全眼境。再融熔时：护目境或是防面护罩HANDLING:Safety glasses.REMELTING:splash goggles or face sheilds.身体Body 再融熔时：工作服REMLTING：coveralls 呼吸 Respiratory防尘口罩，确认使用一个经过认可/证明的口罩或是相等物，当流通的空气不充足时，穿戴适当的口罩。Dust respirator.Be sure to use an approved/certified respirator or equivalent.Wear appropriate respirator when ventilation is inadequate.手 Hands手套(操作时适用)Gloves (suitable to the operation) 脚Feet 不适用其 Not applicable.注解：建议穿上保护的衣物在特定过程中可能是不足够的，使用前麻烦先咨询专家Note：Suggested protective clothing may not be adequate for a specific process.Consult a specialist before using.护目镜,全套的防护衣.护尘口罩.靴子,手套,一个自行控制假如发生大量溢出时的个人安全保护Personal Protection in case of a large Spill呼吸的装置应被除数用来避免产品的吸入,建议用的保护衣物,可能不是很足够;在处理这项产品之前,请先询问专家Splash goggles .Full Suit .Dust respirator. Boots .Gloves.SIGMA
…Solder Bar….
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A self comtained breathing apparatus should be used to avoidinhalation of the product .Suggested protective clothing might not be sufficient ; consult a specialist BEFORE hnadling this product产品名称Product Name (1)锡Tin AnodeExposure Limits 曝露极限TWA：2(mg/m3) Consult local authorizde for acceptable exposure limits.咨询地方当局的专家，可接受的暴露范围九 化学与物理物性（Physical and Chemical Properties)
物理状态与观Physical State and Appearance 分子量Molecular Weight化学式 Chemical Formula 酸检值（1%溶液水）PH（1% Soln Water)酸价 Acid Value沸点/凝结点Boiling Condensation Point熔点/冰点Melting Freerzing Temperature临界温度Critical Temperature蒸气压Vapor Pressure蒸气密度Vapor Density挥发度 Volatility初味Odor Threshold气味Odor 味觉Taste颜色Color比重Specific Gravity蒸发速率Evaporation Rate挥发溶剂有机化合物VOC粘度ViscosityLogKow固态金属不适用Not applicableSn-Cu不适用Not applicable无法提供Not availableTin：2260℃；~227℃无法提供Not available不适用Not applicable无法提供Not available无法提供Not available无法提供Not available无法提供Not applicable无法提供Not applicable银灰色 sliver-grey.7.4(water=1)无法提供Not applicable无法提供Not applicable无法提供Not applicable这个产品在水及油中视不溶解的.The product is insoluble in water and oil非离子 Non-ionic在冷水,热水,甲醇,乙醚,n-辛醇,丙酮中无法被分离Is not dispersed in cole water, hot water, methanol , diethyl ether , n-octanol , acetome电解度(水中)Ionicity (In Water)分散特性Dispersion Properties溶解性Solubility在冷水,热水,甲醇,乙醚,n-辛醇,丙酮是可溶的.Insoluble in cold water,hot water,methanol,diethyl ether,n-octanol,acetone,无法提供.Not applicable十 稳定性与反应特性(Stability and Reactivity)
稳定性与反应特性Stability and ReacitivitySIGMA
本产品是稳定This product is stable…Solder Bar….
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S99.3Cu0.7锡铜无铅高温锡条Solder bar物质安全资料表MSDS
