. 有机合成习题 MeOOMeMeOOCCOOMe1. 合成 TMMeOMeOMeOMeOMeO +MeOOCCH2XCCCOOMeOMeOMeOHO+Ph3POMeOMeOMeCH3CHOOMeOMeOMe+OMeCHOOHOMeAOMeBOHCOMeB'OMeCOOMe( I ) OHOHA'OMeOMeOMePPh3OMeC'( II )MeO( I )CH2BrOMe+( II )MeOOMeMeOOCCCCOOMe?MeOMeOMeOOCCOOMeOMeYMeOMeOMeOOCCOOMeOMe答案：
A: CH3I, OH-
B: CO, HCl, ZnCl2
2. 写出字母代表的化合物的结构：
F
C: CH3CHO, OH-
A’: CH3I, OH- B’: HCHO, HBr, ZnCl2 C’: PPh3, LDA Y: DDQ
O1. AcCl , AlCl3Cl2. NaOClOOEtASOCl2BCH2(COOEt)2Mg(OEt)2CO1. TsOH , ?2. EtOH , H+FClClCOOHDMSOClFHC(OEt)3Ac2ODNH2ENaHNaOHClNHNTMNH答案：
. OFCOOHFCOClFCOOEtCOOEtOCOOHFOCOOEtClClClClClClClClOEtAOFBCOOEtCFDNClClNHHNNETM
3. 写出字母代表的化合物的结构：
OCH31. HOCH2CH2OH , H+2. Ph3P=CHCH3OH3CCH3O1. HSCH2CH2SHCH-
H3COO1. OsO42. TsClOH-ABH3O+C(C13H18O2)Et3N225 oC1. Cr(VI)2. CH3Li3. H+OH3CCH3CH3CH3CH2D1. Ph3CLi2. CH3IE2. LiAlH43. Hg2+ , H2OFN2H4OH- , ?答案：
ATsOOHCH3OH3COO
OCH3O-BOH3CH3COOOOCCH3DCH3CH3CH3CH3H3CCH3OECH3OFCH3OH
4. 写出字母代表的化合物的结构：
CH3OOEtONaOHOOCHN
CH3OAH+BH2OC(C15H21O4N)H2O回流OOH答案：
. OH3COOCH3H3COO-CH2COOH+OHN+NABOCH3CCOOH
5. 写出字母代表的化合物的结构：
BrBrNaCN
ABase.CH3O+D?E(C16H12O2) 七种氢1. HNO32. SOCl2B答案：
OCNCNOOClCN
AOBClCCOOHOOCNDDOCOOHO
6. 写出字母代表的化合物的结构：
HCC-Na+CONH3(l)OHOOMeClAlCl3CHHg2+ , H2OOCH3t-BuONa
OHB(C18H20O2)A(C10H10O2)答案：
OMe
AOOMeBO
7. 写出字母代表的化合物的结构：
CH3ClNHCl2PCl5AlCl32C6H6N
ABC(C22H17N2Cl)答案：
. NCCl3ClCClPh2ClNABCPh2CCl
. 8. 写出字母代表的化合物的结构： OH3CBrOEtCH2(COOEt)2EtONaCNA(C12H20O6)EtONaB(C15H23NO6)EtOHH+EtONa1. H2O , OH- , ?1. NaBH4C(C17H28O8)OD(C15H22O7)2. H3O+ , ?E(C7H10O3)2. H3O+FEtONaGHH2OI(C9H14O3)答案：
H3CCOOEtH3CCOOEtH3CCOOEt
AEtOOCCOOEtCOOEtOBEtOOCCOOEtCNCEtOOCCOOEtCH3COOEtH3CCOOEtCOOHDH3C-EOCH3FOOOCOOEtCH3COO-HOGOOHOIOH3C
9. 写出字母代表的化合物的结构：
PhCOClNKCNH2 , Ni98oC , pressONHNHOt-BuOK80oCH3PO4CyCOClEt3NONNPhClOC6H6 , PyCl
ABC(C19H18N2O2)100oCD答案：
OPhNPhONONNPhON
OACNBNHOPhCDNH
10. 写出字母代表的化合物的结构：
有机合成竞赛知识题
