balance between hydrogen bonding effects and the van der Waals dispersion forces is tipped in favor of the dispersion forces and the remaining hydrogen bonds are stronger due to the closer proximity of the contributing oxygen atoms [655]. Viscosity, then, increases with pressure. The dashed line (opposite) indicates the viscosity minima.
The variation of viscosity with pressure and temperature has been used as evidence that the viscosity is determined more by the extent of hydrogen bonding rather than hydrogen bonding strength.
Self-diffusion is also affected by pressure where (at low temperatures) both the translational and rotational motion of water anomalously increase as the pressure increases.
水的粘度
balancebetweenhydrogenbondingeffectsandthevanderWaalsdispersionforcesistippedinfavorofthedispersionforcesandtheremaininghydrogenbondsarestrongerduetothecloserproximit
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