Synthesis, Structure and Reactivity of
Lanthanocene Complexes
QIAN, Chang-Tao(钱长涛); ZHU, Cheng-Jian(朱成建)
【期刊名称】《《中国化学（英文版）》》 【年(卷),期】2002(020)006 【
摘
要
】
A
variety
of
lanthanocene and
divalent
complexes,e.g.chlorides,hydrocarbyls,amides,hydrides
derivatives,were synthesized by using a series of destgned cyclopentadienyl,indenyl and fluorenyl ligands with ring bridges or dornor-functionalized sidearms.X-Ray crystallographic analyses reveal the formation of intramolecular coordination bonds between central metals and heteroatoms(O,N)in sidearms or bridging chains.Some applications of these complexes are also discussed in this account. 【总页数】17页(519-535)
【关键词】lanthanocene complex; crystal structure; cyclopentadienyl ligand; indenyl ligand; bridging ligand; reduction; polymerization 【作者】QIAN, Chang-Tao(钱长涛); ZHU, Cheng-Jian(朱成建)
【作者单位】State Key Laboratory of Organometallic Chemistry Shanghai Institute of Organic Chemistry Chinese Academy of Sciences Shanghai 200032 China; Department of Chemistry Nanjing University Nanjing 210093 China 【正文语种】中文
Synthesis, Structure and Reactivity of Lanthanocene Complexes
