Synthesis, Crystal Structure and Magnetic Properties of a New 3D Cobalt Vanadate

Synthesis, Crystal Structure and Magnetic Properties of a New 3D Cobalt Vanadate

WANG,Lei(王磊);ZHANG,Hong(张宏);ZHANG,Jing-Ping(张景萍);NIU,Ben(牛犇);CUI,Shu-Xin(崔术新)

【期刊名称】《中国化学（英文版）》 【年(卷),期】2004(022)007

【摘要】A new cobalt vanadate compound 1 [CoⅡ(H2O)2 Vv2 O6] has been hydrothermally synthesized and characterized by the elemental analyses and the single crystal X-ray diffraction analysis. Compound 1 crystallizes in the orthorhombic system, space group Pmna, with a=0.55646, b= 1.06900, c= 1.18452 nm, and Z=4. The magnetic susceptibility of the cobalt vanadate has been measured and indicates possible antiferromagnetic coupling between adjacent cobalt (Ⅱ) (0.5432-0.5697 nm) through bond or space. 【总页数】4页(638-641) 【关键词】cobalt

vanadate;hydrothermal

synthesis;crystal

structure;antiferromagnetic coupling

【作者】WANG,Lei(王磊);ZHANG,Hong(张宏);ZHANG,Jing-Ping(张景萍);NIU,Ben(牛犇);CUI,Shu-Xin(崔术新)

【作者单位】Faculty of Chemistry, Northeast Normal University, Changchun, Jilin 130024, China;Faculty of Chemistry, Northeast Normal University, Changchun, Jilin 130024, China;Faculty of Chemistry,

Northeast Normal University, Changchun, Jilin 130024, China;Faculty of Chemistry, Northeast Normal University, Changchun, Jilin 130024, China;Faculty of Chemistry, Northeast Normal University, Changchun, Jilin 130024, China 【正文语种】中文 【中图分类】 【相关文献】

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