Dimerization of norbornene on zeolite catalysts
N. G. Grigor’eva;S. V. Bubennov;L. M. Khalilov;B. I. Kutepov
【期刊名称】《催化学报》 【年(卷),期】2015(000)003
【摘要】The high activity and selectivity of H‐Beta and H‐ZSM‐12 zeolites in the dimerization of norbornene was established. The norbornene conversion reached 100%in chlorinated paraffin and argon gas medium, with a selectivity of dimer formation of 88%–98%. Four stereo‐isomers of the bis‐2,2’‐norbornylidene structure were identified in the dimer fraction, with the (Z)‐anti‐bis‐2,2’‐norbornylidene prevailing over the others. 【总页数】6页(268-273) 【关键词】
【作者】N. G. Grigor’eva;S. V. Bubennov;L. M. Khalilov;B. I. Kutepov 【作者单位】Federal State Budget Institution of Science, Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 141 prosp. 0ktyabrya, 450075 Ufa, Russian Federation;Federal State Budget Institution of Science, Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 141 prosp. 0ktyabrya, 450075 Ufa, Russian Federation;Federal State Budget Institution of Science, Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 141 prosp. 0ktyabrya, 450075 Ufa, Russian Federation;Federal State Budget