Recent Advances in Iron-Catalyzed C-H Bond Amination via Iron Imido Intermediate

Recent Advances in Iron-Catalyzed C-H Bond

Amination via Iron Imido Intermediate

Peng Wang;Liang Deng

【期刊名称】《中国化学（英文版）》 【年(卷),期】2018(036)012

【摘要】Transition-metal-catalyzed C-H bond amination reaction is an attractive method for the synthesis of amines.Fueled by the growing interests in the development of economical and eco-friendly catalysts for organic transformations,there are great recent efforts on developing iron-catalyzed

C-H

bond

amination

reactions

using

organic

azides,sulfonyl azides,and iminoiodanes as nitrene source.This review summarizes the progress achieved in the field since 2011.The reaction scope,the synthetic utility of the catalytic reaction,and the current mechanistic understandings of the C-H bond amination reactions catalyzed by hemoproteins,iron porphyrins and phthalocyanines,non-heme-type iron complexes,as well as metal-organicframework-supported iron complexes are introduced and discussed. 【总页数】19页(1222-1240) 【关键词】

【作者】Peng Wang;Liang Deng

【作者单位】State Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic

Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China;State Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China 【正文语种】英文 【中图分类】 【相关文献】

1.Recent advances in the iron-catalyzed C-C bond formation via polar reactions

of

alcohols

with

carbon-centered

nucleophiles

[J],

SHANGXiaoJie; LIUZhongQuan

2.Iron（lll）-Catalyzed Direct N-Alkylation of Azoles via Oxidative Transformation of sp3 C H Bonds under Solvent-Free Conditions [J], 刘湘; 陈永欣; 李康宁; 王东; 陈保华

3.Recent advances in the iron-catalyzed cycloaddition reactions [J], WANGChunXiang; WANBoShun

4.Recent advances on iron-catalyzed coupling reactions involving organolithium reagents [J], Zhuliang Zhong; Xiao-Shui Peng; Henry N.C. Wong

5.A Simplified Green Chemistry Approach to the Synthesis of Carbon-Carbon Double Bonds Via Knoevenagel Condensation Catalyzed with

ZrOCl2.8H2O [J], Ali Akbari; Mahsa Amirabedi; Bagher Eftekhari-Sis

以上内容为文献基本信息，获取文献全文请下载