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附录Ⅵ 物质的标准摩尔生成焓、标准摩尔生成吉 布斯函数、标准摩尔熵和摩尔热容(100kPa)>
(1)单质和无机物
物质 ΔfHm(298.15?? ΔfGm(298.15K) -1Sm?(298.15K) J·Kmol-1-1Cp,m?(298.15K) J·K·mol25.48 -1-1K) kJ·mol kJ·mol0 -1 Ag(s) Ag2CO3(s) Ag2O(s) Al(s) Al(g) Al2O3-α Al2(SO4)3(s) Br2(g) Br2(g) Br2(l) C(g) C(金刚石) C(石墨) CO(g) CO2(g) Ca(s) CaC2(s) CaCO3(方解石) CaCl2(s) CaO(s) Ca(OH)2(s) CaSO4(硬石膏) Cl-(aq) Cl2(g) Cu(s) CuO(s) ..
0 -506.14 -30.56 0 313.80 -1669.8 -3434.98 111.884 30.71 0 718.384 1.896 0 -110.525 -393.511 0 -62.8 -1206.87 -795.0 -635.6 -986.5 -1432.68 -167.456 0 0 -155.2 42.712 167.36 121.71 28.315 164.553 0.986 239.3 175.021 245.455 152.3 158.101 2.439 5.694 198.016 213.76 41.63 70.2 92.8 113.8 39.7 76.1 106.7 55.10 222.948 33.32 43.51 -437.09 -10.82 0 273.2 -2213.16 -3728.53 82.396 3.109 0 672.942 2.866 0 -137.285 -394.38 0 -67.8 -1128.70 -750.2 -604.2 -896.89 -1320.24 -131.168 0 0 -127.1 65.57 24.35 79.0 259.4 35.99 35.6 6.07 8.66 29.142 37.120 26.27 62.34 81.83 72.63 48.53 84.5 97.65 33.9 24.47 44.4 .
Cu2O-α F2(g) Fe-α FeCO3(s) FeO(s) Fe2O3(s) Fe3O4(s) H(g) H2(g) D2(g) HBr(g) HBr(aq) HCl(g) HCl(aq) H2CO3(aq) Hl(g) H2O(g) H2O(l) H2O(s) H2O2(l) H2S(g) H2SO4(l) H2SO4(aq) HSO4(aq) l2(g) I2(g) N2(g) NH3(g) NO(g) NO2(g) N2O(g) N2O4(g) N2O5(g) O(g) O2(g) O3(g) -166.69 0 0 -747.68 -266.52 -822.1 -117.1 217.94 0 0 -36.24 -120.92 -92.311 -167.44 -698.7 -25.94 -241.825 -285.838 -291.850 -187.61 -20.146 -811.35 -811.32 -885.75 0 62.242 0 -46.19 89.860 33.85 81.55 9.660 2.51 247.521 0 142.3 -146.33 0 0 -673.84 -244.3 -741.0 -1014.1 203.122 0 0 -53.22 -102.80 -95.265 -131.17 -623.37 -1.32 -228.577 -237.142 (-234.03) -118.04 -33.040 (-866.4) 100.8 203.5 27.15 92.8 54.0 90.0 146.4 114.724 130.695 144.884 198.60 80.71 186.786 55.10 191.2 206.42 188.823 69.940 (39.4) 102.26 205.75 156.85 69.8 31.46 25.23 82.13 51.1 104.6 143.42 20.80 28.83 29.20 29.12 29.12 29.12 33.571 75.296 82.29 33.97 137.57 -752.99 0 19.34 0 -16.603 90.37 51.86 103.62 98.39 110.5 230.095 0 163.45 126.86 116.7 260.60 191.598 192.61 210.309 240.57 220.10 304.42 342.4 161.063 205.138 237.7 55.97 36.87 29.12 35.65 29.861 37.90 38.70 79.0 108.0 21.93 29.37 38.15 ..
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OH-(aq) S(单斜) S(斜方) (g) S(g) SO2(g) SO3(g) SO4 (aq) 2--229.940 0.29 0 124.94 222.80 -296.90 -395.18 -907.51 -157.297 0.096 0 76.08 182.27 -300.37 -370.40 -741.90 -10.539 32.55 31.9 227.76 167.825 248.64 256.34 17.2 23.64 22.60 32.55 39.79 50.70
(2)有机化合物
Cp,m?( ΔfHm?(298.15K) ΔfGm?(298.15K) Sm?(298.15K) 298.15 物质 K) J·K-1kJ·mol-1 kJ·mol-1 J·Kmol-1-1 ·mol-1 烃 类 CH4(g), 甲烷 -74.847 50.827 186.30 35...