Facile synthesis of Mo2C nanoparticles on N-doped carbon nanotubes with enhanced electroca
Facile synthesis of Mo2C nanoparticles on N-doped carbon nanotubes with enhanced electrocatalytic activity for hydrogen evolution and oxygen
reduction reactions
Yue-Jun Song; Jin-Tao Ren; Gege Yuan; Yali Yao; Xinying Liu; Zhong-Yong Yuan
【期刊名称】《能源化学:英文版》 【年(卷),期】2019(028)011
【摘要】Developing low-cost and highly-efficient electrocatalysts for renewable energy conversion technologies has attracted even-increasing attention. Molybdenum carbide materials have recently emerged as a type of promising catalysts for electrocatalytic reactions due to the earth-abundance and Pt-resembled electrical properties. In this work, taking the advantage of the interaction between the basic groups of the Mo(VI)-melamine polymer and the acidic groups on the surface of the oxidized carbon nanotubes(CNTs), N-doped CNTs supported Mo2C nanoparticles(Mo2C/NCNT) are prepared, which exhibit outstanding electrocatalytic activity and durability for both the hydrogen evolution and oxygen reduction reactions. The impressive performance of Mo2C/NCNT can be attributed to the small size of Mo2C particles, the large exposure ratio of surface sites and the presence of N-doped CNTs. This work enlarges the multi-field applications of molybdenum carbide-base materials as promising non-
precious metal electrocatalysts, which is of great significance for sustainable energy-related technologies. 【总页数】10页(P.68-77)
【关键词】N-doping; Carbon nanotubes; Molybdenum carbides; Hydrogen
evolution
reaction;
Oxygen
reduction
reaction;
Electrocatalysis
【作者】Yue-Jun Song; Jin-Tao Ren; Gege Yuan; Yali Yao; Xinying Liu; Zhong-Yong Yuan
【作者单位】Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education) National Institute for Advanced Materials School of Materials Science and Engineering Nankai University Tianjin 300350 China; Material and Process Synthesis College of Science Engineering and Technology University of South Africa Johannesburg South Africa 【正文语种】中文 【中图分类】TG1 【文献来源】
https://www.zhangqiaokeyan.com/academic-journal-cn_journal-energy-chemistry_thesis/0201278121629.html 【相关文献】
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