SAFETY DATA SHEETS
According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition
1.Identification
1.1GHS Product identifier
Product name
Germanium tetrachloride
1.2Other means of identification
Product number Other names
-
germanium(IV) tetrachloride
1.3Recommended use of the chemical and restrictions on use
Identified uses
Uses advised against
1.4Supplier's details
Company Address Telephone Fax
1.5Emergency phone number
For industry use only. no data available
Emergency phone number Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT
hours).
2.Hazard identification 2.1Classification of the substance or mixture
Corrosive to metals, Category 1 Skin corrosion, Category 1A
Specific target organ toxicity – single exposure, Category 3
2.2GHS label elements, including precautionary statements
Pictogram(s)
Signal word
Hazard statement(s)
Precautionary statement(s) Prevention
Response Storage
Disposal
Danger
H290 May be corrosive to metals
H314 Causes severe skin burns and eye damage H335 May cause respiratory irritation
P234 Keep only in original packaging.
P260 Do not breathe dust/fume/gas/mist/vapours/spray. P264 Wash ... thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P271 Use only outdoors or in a well-ventilated area.
P390 Absorb spillage to prevent material damage.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P363 Wash contaminated clothing before reuse.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P310 Immediately call a POISON CENTER/doctor/… P321 Specific treatment (see ... on this label).
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312 Call a POISON CENTER/doctor/…if you feel unwell.
P406 Store in a corrosion resistant/...container with a resistant inner liner.
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container to ...
2.3Other hazards which do not result in classification
none
3.Composition/information on ingredients 3.1Substances
Chemical name Common names and synonyms CAS number EC number Concentration Germanium tetrachloride Germanium tetrachloride 10038-98-9 none 100% 4.First-aid measures 4.1Description of necessary first-aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2Most important symptoms/effects, acute and delayed
no data available
4.3Indication of immediate medical attention and special
treatment needed, if necessary
no data available
5.Fire-fighting measures 5.1Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2Specific hazards arising from the chemical
no data available
5.3Special protective actions for fire-fighters
Wear self-contained breathing apparatus for firefighting if necessary.
6.Accidental release measures 6.1Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8.
6.2Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.
6.3Methods and materials for containment and cleaning up
Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.
7.Handling and storage 7.1Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.
7.2Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
8.Exposure controls/personal protection 8.1Control parameters
Occupational Exposure limit values
no data available
Biological limit values
no data available
8.2Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
8.3Individual protection measures, such as personal protective equipment (PPE)
Eye/face protection
Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
Respiratory protection
Wear dust mask when handling large quantities.
Thermal hazards
no data available
9.Physical and chemical properties Physical state Colorless, fuming liquid Colour no data available Odour no data available Melting point/ freezing -49.5oC point
Boiling point or initial 83°C(lit.) boiling point and boiling range
Flammability no data available Lower and upper explosion no data available limit / flammability limit
Flash point no data available Auto-ignition no data available temperature Decomposition no data available temperature pH no data available Kinematic viscosity no data available Solubility no data available Partition coefficient no data available n-octanol/water (log value)
Vapour pressure no data available Density and/or relative 1.844g/mLat 25°C
四氯化锗安全技术说明书英文
