Synthesis,Crystal Structure and Magnetic Properties of Novel Three-dimensional Frameworks

Synthesis,Crystal Structure and Magnetic Properties of Novel Three-dimensional

Frameworks [Mn(PDC)H2O]n

GAO En-Jun;GU Xiao-Fu;SUN Ya-Guang;YIN Hong-Xi;WU Qiong;LIU Lei;ZHU Ming-Chang;ZHANG Wan-Zhong

【期刊名称】《中国化学（英文版）》 【年(卷),期】2008(026)011 【

摘

要

】

A

novel

coordination

polymer,[Mn(PDC)H2O]n(1)(H2PDC=pyridine-2,3-dicarboxylic acid),has been hydrothermally synthesized and characterized by elemental analysis,IR and single crystal X-ray diffraction.X-ray single crystal structural analyses revealed that two-dimensional frameworks were formed,and further assembled into a three-dimensional supramolecular structure bridged by PDC ligands.Moreover,the magnetic study of complex 1 shows weak antiferromagnetic interaction between the neighboring Mn(Ⅱ)centers within the chains and even weak ferromagnetic interactions between the Mn(Ⅱ)centers in different chains.

【总页数】4页(2133-2136) 【

关

键

词

】

manganese(Ⅱ),coordination

polymer,crystal

structure,magnetic property

【作者】GAO En-Jun;GU Xiao-Fu;SUN Ya-Guang;YIN Hong-Xi;WU

Qiong;LIU Lei;ZHU Ming-Chang;ZHANG Wan-Zhong

【作者单位】Laboratory of Coordination Chemistry,Shenyang Institute of Chemical Technology,Shenyang,Liaoning 110142,China;Laboratory of Coordination

Chemistry,Shenyang

Institute

of

Chemical

of

Technology,Shenyang,Liaoning Coordination

110142,China;Laboratory

Institute

of

Chemistry,Shenyang Chemical

of

Technology,Shenyang,Liaoning Coordination

110142,China;Laboratory

Institute

of

Chemistry,Shenyang Chemical

of

Technology,Shenyang,Liaoning Coordination

110142,China;Laboratory

Institute

of

Chemistry,Shenyang Chemical

of

Technology,Shenyang,Liaoning Coordination

110142,China;Laboratory

Institute

of

Chemistry,Shenyang Chemical

of

Technology,Shenyang,Liaoning Coordination

110142,China;Laboratory

Institute

of

Chemistry,Shenyang Chemical

of

Technology,Shenyang,Liaoning Coordination

110142,China;Laboratory

Institute

of

Chemistry,Shenyang Chemical

Technology,Shenyang,Liaoning 110142,China 【正文语种】中文 【中图分类】O6 【相关文献】

1.Synthesis, Structure, Thermal and Magnetic Properties of a New Open-framework Borophosphate: NH4Mn(H2O)2BP2O8·H2O [J], SHI,Heng-

Zhen; CHANG,Jia-Zhong; TANG-BO,HeJin; DING,Han-Ming; SHAN,Yong-Kui

2.Synthesis and Crystal Structure of a Two-dimensional Framework Supramolecular Complex [Mn(phen)(DPZDA)(H2O)]·2H2O [J], SUN Ya-Guang; GU Xiao-Fu ; GAO En-Jun; CHEN Shang-Dong

3.Synthesis and Structure of One Novel Polyoxometalate Compound Connected via Cerium(Ⅲ) Cation with Three-dimensional Framework H2{[K(H2O)2]2[Ce(H2O)5]2(H2Mo1.16W10.84O42)}·8H2O [J],

4.Hydrothermal Synthesis and Crystal Structure of a Novel Selenite-chloride：[Cd4（SeO3）2Cl4（H2O）]n with a Three-dimensional Framework [J], CHEN Wen-Tong; WEI Kun-Yu; MIAO Xiao-Fei

5.Synthesis, crystal structures, and magnetic properties of two three-dimensional octacyanotungstate(IV)- based bimetallic frameworks with 4,4′-bipyridine dioxide (4,4′-dpdo) [J],

以上内容为文献基本信息，获取文献全文请下载