Synthesis and Structure of the First Protonated Zincoborophosphate：( H3O ) Zn( H2O

Synthesis and Structure of the First Protonated Zincoborophosphate：（ H3O ） Zn（ H2O ）

2BP2O8·H2O

石恒真;单永奎;何鸣元;刘煜炎;翁林红

【期刊名称】《中国化学：英文版》 【年(卷),期】2003(021)009

【摘要】The solid add of the first protonated zincoborophosphate,(H3O) Zn (H2O)2BP2O8·H2O (1), was soventothermally syn-thesized by the reaction of Zn (NO3)2·6H2O and H3BO3 with H3PO4 in a mixed solvent, and structurally characterized by single-ystal X-ray diffraction analysis. It crystallizes in thehexagonal P6122, a = 0.9604(4) nm, c = 1.5297(6) nm, V =1.2218(8) nm3, Dc = 2.921 g/cm3, Z = 6, F (000) = 1080,μ=3.495 mm-1. The stmchwe features that the tetrahedra-te-trahedra hdlces interconnected by octahedra and strong hydro-gem bond interactions form a three-dimensional framework.The protonated water molecules are located at unique positions.other characterizations by IR and thermal analysis are also de-scribed. 【总页数】4页(1170-1173)

【关键词】（H3O）Zn（H2O）2BP2O8·H2O;合成;结构;质子化;螺旋带状物;硼磷酸锌化合物

【作者】石恒真;单永奎;何鸣元;刘煜炎;翁林红 【

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vDepartmentofChemistry,EastChinaNormalUniversity,Shanghai200062,China;LaboratoryforQuantumOpticsofNationalEducationMinistry,-EastChinaNormalUniversity,Shanghai200062,China;DepartmentofChemistry,FudanUniversity,Shanghai200433,China 【正文语种】英文 【中图分类】O614.241 【相关文献】

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