A new class of rhodium complexes containing free donor atoms rnand their intramolecular su

A new class of rhodium complexes containing free

donor atoms rnand their intramolecular

substitution reaction

JIANG, Hua;YUAN, Guo-Qing;ZHANG, Shu-Feng;PAN, Ping-Lai;DIAO, Kai-Sheng

【期刊名称】《中国化学（英文版）》 【年(卷),期】2000(018)005

【摘要】A new class of rhodium complexes with high catalytic activity rnas well as excellent stability, which was used as catalyst for rncarlbonylation of methanol to acetic acid, is reported. It conrntains free donor (namely un-coordinated donor) atoms which rnenable to improve its stability by intramolecular substitution rnrearction. Its synthesis, characteristic and catalytic reaction rnwere discussed here. 【总页数】5页(751-755)

【关键词】Rhodium complex;substitution reaction;acetic rnacid;catalytic stability

【作者】JIANG, Hua;YUAN, Guo-Qing;ZHANG, Shu-Feng;PAN, Ping-Lai;DIAO, Kai-Sheng

【作者单位】Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China;Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China;Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China;Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China;Guangxi Institute for