SAFETY DATA SHEETS
According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition
1.Identification
1.1GHS Product identifier
Product name
palladium(II) chloride
1.2Other means of identification
Product number Other names
-
Palladium(II) Chloride
1.3Recommended use of the chemical and restrictions on use
Identified uses
Uses advised against
1.4Supplier's details
Company Address Telephone Fax
1.5Emergency phone number
For industry use only. no data available
Emergency phone number Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT
hours).
2.Hazard identification 2.1Classification of the substance or mixture
Corrosive to metals, Category 1 Acute toxicity - Oral, Category 4 Skin sensitization, Category 1 Serious eye damage, Category 1
Hazardous to the aquatic environment, short-term (Acute) - Category Acute 1 Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 1
2.2GHS label elements, including precautionary statements
Pictogram(s)
Signal word
Hazard statement(s)
Precautionary statement(s) Prevention
Response Storage
Danger
H290 May be corrosive to metals H302 Harmful if swallowed
H317 May cause an allergic skin reaction H318 Causes serious eye damage H400 Very toxic to aquatic life
H410 Very toxic to aquatic life with long lasting effects
P234 Keep only in original packaging. P264 Wash ... thoroughly after handling.
P270 Do not eat, drink or smoke when using this product. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P273 Avoid release to the environment.
P390 Absorb spillage to prevent material damage.
P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/…if you feel unwell. P330 Rinse mouth.
P302+P352 IF ON SKIN: Wash with plenty of water/... P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P321 Specific treatment (see ... on this label).
P362+P364 Take off contaminated clothing and wash it before reuse. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor/… P391 Collect spillage.
P406 Store in a corrosion resistant/...container with a resistant inner
liner.
Disposal
P501 Dispose of contents/container to ...
2.3Other hazards which do not result in classification
none
3.Composition/information on ingredients 3.1Substances
Chemical name Common names and synonyms CAS number EC number Concentration palladium(II) chloride palladium(II) chloride 7647-10-1 none 100% 4.First-aid measures 4.1Description of necessary first-aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2Most important symptoms/effects, acute and delayed
SYMPTOMS: This compound causes corneal irritation. ACUTE/CHRONIC HAZARDS: This compound is an eye irritant.
4.3Indication of immediate medical attention and special
treatment needed, if necessary
Basic treatment: Establish a patent airway. Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if needed. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for pulmonary edema and treat if necessary ... . Monitor for shock and treat if necessary ... . Anticipate seizures and treat if necessary ... . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with normal saline during transport ... . Do not use emetics. For ingestion, rinse mouth and administer 5 ml/kg up to 200
ml of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool ... . Cover skin burns with dry sterile dressings after decontamination ... . /Poison A and B/
5.Fire-fighting measures 5.1Extinguishing media
Suitable extinguishing media
Fires involving this compound should be controlled using a dry chemical carbon dioxide or Halon extinguisher.
5.2Specific hazards arising from the chemical
Flash point data for this chemical are not available. It is probably combustible.
5.3Special protective actions for fire-fighters
Wear self-contained breathing apparatus for firefighting if necessary.
6.Accidental release measures 6.1Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8.
6.2Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.
6.3Methods and materials for containment and cleaning up
Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.
7.Handling and storage 7.1Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.
7.2Conditions for safe storage, including any incompatibilities
Keep tightly closed. /Dihydrate/
8.Exposure controls/personal protection 8.1Control parameters
Occupational Exposure limit values
no data available
Biological limit values
no data available
8.2Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
8.3Individual protection measures, such as personal protective equipment (PPE)
Eye/face protection
Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
Respiratory protection
Wear dust mask when handling large quantities.
Thermal hazards
no data available
9.Physical and chemical properties Physical state dark brown powder Colour Red rhombic crystals; hygroscopic Odour no data available Melting point/ freezing 678-680oC point
Boiling point or initial 100oC boiling point and boiling range
Flammability no data available Lower and upper explosion no data available limit / flammability limit
Flash point no data available
氯化钯安全技术说明书英文



