LiNix Co1-xO2合成条件对-其结构与性能的影响
邹正光;麦立强;陈寒元;彭忠东
【期刊名称】《材料科学与工艺》 【年(卷),期】2001(009)001
【摘要】研究了在空气下固相合成LiNixCo1-xO2的工艺及反应预处理方式、不同锂源、温度、时间和配比等因素对产品结构与性能的影响．结果表明：采用LiOH为锂源、采取混合研磨后压块以及烘干Ni(OH)2、Co(OH)2后加入氢氧化锂的预处理方式更有利于合成反应的进行；在600℃预烧一段时间的条件下，750℃恒温合成的产物比650℃、850℃保温合成的产物层状结构更明显，首次充电容量更高；在一定范围内，随合成时间的增长，产物的衍射峰强度增大，结构更完整，电性能更好；按镍钴的不同配比，均能合成结构良好的LiNixCo1-xO2，而配比为n(Li):n(Ni):n(Co)=1.15:0.3:0.7时合成的产物初始容量较高，达到156.146 mAh/g.%To prepare cheaper and better cathode materials for lithium ion battery, LiNi x Co 1-x O2 (0 ≤ x ≤ 1 )was studied and synthesized in solid phase in air. The effect of pretreatment method, lithium resource, synthe-sis temperature, heat treatment time and ratio of raw materials on the products were discussed. The resultsshow that the use of LiOH as lithium resource and making extrusion molding after mixing and grinding raw andprocessed materials are beneficial to synthesize the samples. The products preheated at 600 ℃ and then sin-tered under constant temperature at 750 ℃ is better than those sintered under constant temperature at
LiNix Co1-xO2合成条件对-其结构与性能的影响
