Synthesis, Structure and Conductivity of
(PyH)[Ni(dmit)2]2
Wen XU;Dao Ben ZHU;Qi FANG;Gang XUE;Wen Tao YU;Hong Yu CHEN;Guo Qun LIU;Wei XU;Cui Ying XU;De Qing ZHANG
【期刊名称】《中国化学快报（英文版）》 【年(卷),期】2003(014)010
【摘要】A new molecular conductor (PyH)[Ni(dmit)2]2 (dmit = 4, 5-dimercapto-1, 3-dithiole-2-thione) has been prepared and its crystal structure has been determined. Crystallographicparameters for (PyH)[Ni(dmit)2]2: C17H6NNi2S20; triclinic system; P-1 space group; a = 5.9227 (4),b =8.2279 (6), c = 16.7535 (9) A, α= 90.233 (5)°, β= 92.107 (6)°, γ= 104.654 (6) °; V= 789.25(9) A3; Z = 1; Dc = 2.068 g/cm3; F (000) = 491. The conductivity at one direction on (001) planeat room temperature was measured to be 0.13 Ω-1@cm-1. The resistivity-temperature curve in thetemperature range of 90～290 K shows that this compound behaves as a semiconductor. 【总页数】4页(1089-1092) 【
关
键
词
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Molecular
conductor;synthesis;electrical
conductivity;semiconductor;structure
【作者】Wen XU;Dao Ben ZHU;Qi FANG;Gang XUE;Wen Tao YU;Hong Yu CHEN;Guo Qun LIU;Wei XU;Cui Ying XU;De Qing ZHANG
【作者单位】State Key Laboratory of Crystal Materials, Shandong
University, Jinan 250100;State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100;State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100;State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100;State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100;State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100;Institute of Chemistry, The Chinese Academy of Sciences, Beijing 100080;Institute of Chemistry, The Chinese Academy of Sciences, Beijing 100080;Institute of Chemistry, The Chinese Academy of Sciences, Beijing 100080;Institute of Chemistry, The Chinese Academy of Sciences, Beijing 100080
【正文语种】中文 【中图分类】O6 【相关文献】
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Synthesis, Structure and Conductivity of (PyH)[Ni(dmit)2]2
