无柄新乌檀中的配糖体
康文艺;李昕;杨小生;郝小江
【期刊名称】《天然产物研究与开发》 【年(卷),期】2004(016)002
【摘要】从无柄新乌檀乙醇浸膏的正丁醇部位分离得到7个已知配糖体化合物,经波谱分析为:喹诺酸-3-O-β-D-葡萄吡喃糖基(28→1)-β-D-葡萄吡喃糖酯(1),齐墩果酸-(28→1)-β-D-葡萄吡喃糖酯(2),熊果酸-(28→1)-β-D-葡萄吡喃糖酯(3),喹诺酸-3-O-β-D-葡萄吡喃糖基-(1→3)-6-去氧-β-葡萄吡喃糖苷(4),齐墩果酸-3-O-β-D-吡喃木糖基-(1→2)-β-D-葡萄吡喃糖基-28-O-β-D-葡萄吡喃糖酯(5),番木鳖甙(6),7-甲氧基-龙胆苦甙(7).这些化合物均为首次从该属中分离得到.%Seven known conpoundls were isolated from the n-BuOH fraction of the stems of Neonauclea sessilifolia(Roxb.) Merr, and their structures were elucidated by means of spectroscopic method as quinovic acid-3-O-β-D-glucopyranosyl-
(28--→1)-β-D-glucopyranosyl
ester(
1
),
oleanolic acid- ( 28 → 1 )-β-D-glucopyranosyl ester(2), ursolicacid-(28→1)-β-D-glucopyranosyl
ester(3),
quinovic
acid-3-O-β-D-
glucopyranosyl( 1→3)-6-deoxy-β-glucopyranoside(4), oleanic acid-3-O-β-D-xylopyranosyl-( glucopyranosyl
1
→ (
5 2 ),
)-β-D-glucopyranoside-28-O-β-D-iridoidloganin(6),
7-methoxy-
ester
gentiopicroside(7). All of them were isolated from the genus for the first time.
【总页数】4页(107-110)
无柄新乌檀中的配糖体
