制药工业挥发性有机物治理
实用手册
生态环境部大气环境司编《制药工业挥发性有机物治理
实用手册（一）》
参与编制人员
严刚秦承华王宁统稿：王凤王浩雷宇宁淼蔡俊江梅刘通浩郑伟宁淼郑伟刘锐源张国宁庄思源黄皓旻强叶代启马目录
第1部分制药工业VOCS排放控制技术指南....................................................................................1一、源头削减...........................................................................................................................................1（一）生产工艺...................................................................................................................................1（二）生产设备...................................................................................................................................2二、过程控制...........................................................................................................................................2（一）储存...........................................................................................................................................2（二）输送...........................................................................................................................................3（三）投料...........................................................................................................................................3（四）取样...........................................................................................................................................4（五）蒸馏/精馏..................................................................................................................................4（六）母液收集...................................................................................................................................4（七）干燥...........................................................................................................................................4（八）真空设备...................................................................................................................................5（九）设备组件...................................................................................................................................5（十）废水...........................................................................................................................................5（十一）循环冷却水...........................................................................................................................6（十二）非正常工况...........................................................................................................................6三、末端治理...........................................................................................................................................7（一）储罐...........................................................................................................................................7（二）工艺过程...................................................................................................................................7（三）废水...........................................................................................................................................7（四）非正常工况...............................................................................................................................7四、排放限值...........................................................................................................................................7五、监测监控...........................................................................................................................................8六、台账记录...........................................................................................................................................8（一）原辅料信息...............................................................................................................................8（二）生产台账...................................................................................................................................8（三）泄漏检测与修复.......................................................................................................................9（四）储罐...........................................................................................................................................9（五）装载...........................................................................................................................................9（六）循环水冷却系统.......................................................................................................................9（七）废水集输、储存与处理系统...................................................................................................9（八）治理设施运行信息.................................................................................................................10（九）非正常工况.............................................................................................................................10附件：常见有机化学品25℃下的饱和蒸气压参考表........................................................................11第2部分VOCS相关标准内容要点...................................................................................................14一、产品质量标准以及内容要点.........................................................................................................14（一）标准.........................................................................................................................................14（二）内容要点.................................................................................................................................14二、无组织排放控制标准解释说明.....................................................................................................19第3部分VOCS末端治理技术选择与运行维护要求.......................................................................26一、治理技术适用范围.........................................................................................................................26二、治理设施运行维护.........................................................................................................................32三、治理设施台账记录.........................................................................................................................40（一）设施运行管理信息.................................................................................................................40（二）非正常工况信息.....................................................................................................................41（三）日常维护信息.........................................................................................................................42第4部分重点行业VOCS排放监测技术指南..................................................................................43一、监测内容、指标、频次的确定....................................................................................................43（一）监测内容的确定.....................................................................................................................43（二）监测指标的确定.....................................................................................................................44（三）监测频次的确定.....................................................................................................................441、排污单位自行监测的频次.......................................................................................................442、监督帮扶抽查监测的频次.......................................................................................................44二、排污口规范化设置要求................................................................................................................45（一）排污口规范化设置的通用要求.............................................................................................45（二）采样位置要求.........................................................................................................................46（三）采样平台要求.........................................................................................................................47（四）采样平台通道要求.................................................................................................................47（五）采样孔要求.............................................................................................................................48三、监测要求.........................................................................................................................................49（一）手工监测要求.........................................................................................................................49（二）自动监测要求.........................................................................................................................511、自动监测的安装等管理要求...................................................................................................512、自动监测的关键技术要求.......................................................................................................52四、监测记录.........................................................................................................................................53（一）手工监测的记录要求.............................................................................................................53（二）自动监测的记录要求.............................................................................................................53第1部分制药工业VOCs排放控制技术指南图1-1发酵制药生产工艺与VOCs排放环节图图1-2化学合成制药生产工艺与VOCs排放环节图图1-3提取制药生产工艺与VOCs排放环节图一、源头削减
（一）生产工艺?使用非卤代烃和非芳香烃类溶剂，生产水基、乳液、颗粒产品。?采用生物酶法合成技术。
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制药工业挥发性有机物治理实用手册-生态环境部 - 图文
