Synthesis and Properties of Novel Poly(amine
ether)s
CHANG,Guan-Jun;XU,Zhe;LIN,Run-Xiong;LUO,Xuan
【期刊名称】《中国化学（英文版）》 【年(卷),期】2007(025)008
【摘要】Using aromatic bis(4-bromophenyl) ether and various aromatic diamines as the monomers, a series of novel poly(amine ether)s (PAEs) have been synthesized via palladium-catalyzed aryl amination, which is the Hartwig-Buchwald polycondensation reaction. Their structures were characterized by means of elemental analysis,FT-IR, 1H NMR and UV-Vis spectroscopy. The results show a good agreement with the proposed structures. Their general properties were studied by DSC and TG, and it's obvious that they show high glass transition temperatures (Tg＞200 C), good thermal stability with high decomposition temperatures (TD＞500 ℃) and excellent solubility.The mechanical behavior of these polymers suggested that they could be considered a new class of high-performance polymers. 【总页数】5页(1207-1211)
【关键词】bis(4-bromophenyl) ether, palladium-catalyzed aryl amination, high-performance, poly(amine ether)s
【作者】CHANG,Guan-Jun;XU,Zhe;LIN,Run-Xiong;LUO,Xuan
【作者单位】Key Laboratory of Rubber-plastics of Ministry of Education,
Qingdao University of Science and Technology, Qingdao, Shandong 266042, China;Key Laboratory of Rubber-plastics of Ministry of Education, Qingdao University of Science and Technology, Qingdao, Shandong 266042, China;Key Laboratory of Rubber-plastics of Ministry of Education, Qingdao University of Science and Technology, Qingdao, Shandong 266042, China;China Academy of Engineering Physics, Mianyang, Sichuan 621900, China 【正文语种】中文 【中图分类】O6 【相关文献】
1.Synthesis and Properties of Poly （N-isopropylacrylamide） and Poly （N-isopropylacrylamide-co-acrylamide） Hydrogels [J], 裴勇; 陈捷; 杨黎明; 施丽莉; 罗浩杰
2.Poly（L—lactide）—Poly（ethylene glycol） Multiblock Copolymers：Synthesis and Properties [J], WeiJunLuo; SuMingLi; 等
3.Synthesis and properties of novel soluble poly(aryl amine ketone)s as high-performance polymers [J],
4.Synthesis and properties of poly(1-phenyl-1-octyne)s containing stereogenic and chromophoric pendant groups [J], LAM; Jacky; W.Y.; JIM; Cathy; K.W.; KWOK; Hoi; Sing
5.Synthesis and Photovoltaic Properties of Poly(5,6-bis(octyloxy)-4,7-di(thiophen-2-yl)benzo-[c] [1,2,5]-thiadiazole-9,9-dioctylfluorene) [J],
Liwei Wang; Feiyao Qing; Yeping Sun; Xiaoyu Li; Haiqiao Wang
以上内容为文献基本信息，获取文献全文请下载
Synthesis and Properties of Novel Poly(amine ether)s
