A Review on Complete Oxidation of Methane at
Low Temperatures
Zhenhua Li;Gar B. Hoflund
【期刊名称】《天然气化学(英文版)》 【年(卷),期】2003(012)003
【摘要】This paper reviews recent developments in complete oxidation of methane at low temperatures over noble metal catalysts in the past 20 years. The Pd/Al2O3 catalyst system is fully discussed. The review mainly focuses on the kinetic aspects of methane oxidation over this catalyst, and methane activation behavior over Pd and PdO phases (the form of PdO on the surface, transient behavior, the nature of the active sites, the influence of metal particle size and their structure sensitivities, and so on). Some Pd catalysts supported on other oxides besides the Al2O3 support are briefly discussed. Possible routes of non-noble metal catalysts as substitutes for the Pd catalyst are also proposed. 【总页数】8页(153-160) 【
关
键
词
】
methane;complete
oxidation;review;Pd;low
temperature;noble metal
【作者】Zhenhua Li;Gar B. Hoflund
【作者单位】State Key Lab of C1 Chemistry and Technology, School of Chemical
Engineering,
Tianjin
University,
Tianjin
300072,
China;Department of Chemical Engineering, University of Florida, USA
【正文语种】中文 【中图分类】TE64 【相关文献】
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