Crystal Structure and Magnetic Property of Heteronuclear Copper-Lanthanum Carboxylate Complex

Crystal Structure and Magnetic Property of Heteronuclear Copper-Lanthanum Carboxylate

Complex

WU,Bin(吴斌); LU,Wei-Min(陆维敏); ZHENG,Xiao-Ming(郑小明)

【期刊名称】《《中国化学（英文版）》》 【年(卷),期】2002(020)009

【摘要】The title complex, [CuLaL5(phen) (C2H5OH)]2 (where L=α-methylacrylato; phen= 1,10-phenanthroline), has been prepared and its structure has been determined by X- ray diffraction analysis. The complex ctystallizes in triclinic system with space group P1. Crystal data: a = 1.2725 (3) nm,b = 1.4421(4) nm, c = 1.2109(2) nm, α = 109.48(2)°, β =115.26(2)°, γ=66.42(2)°. The complex is a discrete tetranuclear CuLaLaCu molecule bridged by α-methylacrylato groups.Magnetic property of the complex was also measured and discussed. 【总页数】5页(846-850)

【关键词】copper; lanthanum; heteronuclear; crystal sttuc-ture; magnetic property

【作者】WU,Bin(吴斌); LU,Wei-Min(陆维敏); ZHENG,Xiao-Ming(郑小明) 【作者单位】Institute of Catalysis Zhejiang University Xixi Campus Hangzhou Zhejiang 310028 China 【正文语种】中文 【中图分类】

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