On the fluorescence enhancement mechanism of Er3+ in germanate glass containing silver particles

On the fluorescence enhancement mechanism of Er3+ in germanate glass containing silver particles

Li Xiang-Ping;Chen Bao-Jiu;Shen Ren-Sheng;Zhang Jin-Su;Sun Jia-Shi;Cheng Li-Hong;Zhong Hai-Yang

【期刊名称】《中国物理：英文版》 【年(卷),期】2013(022)002

【摘要】The spectral properties of trivalent erbium ions (Er3+) are systematically studied in a melt-quenched germanate glass (60 GeO2-20PbO-10BaO-10K2O-0.1Ag2O) containing silver (Ag) particles.Thermal treatment of the material leads to the precipitation of Ag particles as observed by transmission electron microscopy and confirmed by absorption spectrum for the obvious surface plasmon resonance peak of Ag particles.The fluorescence from Er3+ in the 10-min-annealed sample with Ag particles is found to be 4.2 times enhanced compared with the unannealed sample excited by 488-nm Ar+ laser.A comparison is made between a spectral study performed on the unannealed Er3+-doped sample and the one annealed for 20 rnin.The data of absorption cross section and Judd-Ofelt intensity parameters show the agreement between the two samples no matter whether there are Ag particles,indicating that the introduction of Ag particles by post-heat treatment has no effect on the crystal field environment of Er3+ ions.The fluorescence enhancement is attributed to the surface plasmon