实用文档
无机化合物的标准热力学数据
Standard Thermodynamic Data of Inorganic Compounds
下表中的标准热力学数据是以温度25.0℃(298.15K)处于标准状态的1摩尔纯物质为基准的。 物质状态表示符号为:g—气态,l—液态,cr—晶体。
Θ
△Hf——物质的标准生成焓(298.15K),单位为kJ/mol;
Θ
△Gf——物质的标准生成Gibbs自由能(298.15K),单位为kJ/mol;
Θ
S——物质的标准熵(298.15K),单位为J/(mol·K);
CpΘ ——物质的常压热容(298.15K),单位为J/(mol?K)。
无机化合物的标准热力学数据
Standard Thermodynamic Data of Inorganic Compounds Θ Θ 状态△Hf △Gf SΘ CpΘ 分子式 (State) /(kJ/mol) /(kJ/mol) /[J/(mol?K)] /[J/(mol?K)] cr 0.0 - 56.5 27.2 Ac g 406.0 366.0 188.1 20.8 Ag Ag AgBr AgBrO3 AgCl AgClO3 AgClO4 AgCN Ag2CO3 Ag2CrO4 AgF AgI AgIO3 AgNO3 Ag2O Ag2S Ag2SO4 Al AlBr3 AlCl3 AlF3 AlI3 Al2O3 AlPO4 cr g cr cr cr cr cr cr cr cr cr cr cr cr cr cr cr cr g cr g cr g cr g cr g cr cr 0.0 284.9 -100.4 -10.5 -127.0 -30.3 -31.1 146.0 -505.8 -731.7 -204.6 -61.8 -171.1 -124.4 -31.1 -32.6 -715.9 0.0 330.0 -527.2 -425.1 -704.2 -583.2 -1510.4 -1204.6 -313.8 -207.5 -1675.7 -1733.8 - 246.0 -96.9 71.3 -109.8 64.5 - 156.9 -436.8 -641.8 - -66.2 -93.7 -33.4 -11.2 -40.7 -618.4 - 289.4 - - -628.8 - -1431.1 -1188.2 -300.8 - -1582.3 -1617.9 42.6 173.0 107.1 151.9 96.3 142.0 - 107.2 167.4 217.6 - 115.5 149.4 140.9 121.3 144.0 200.4 28.3 164.6 - - 110.7 - 66.5 277.1 159.0 - 50.9 90.8 25.4 20.8 52.4 - 50.8 - - 66.7 112.3 142.3 - 56.8 102.9 93.1 65.9 76.5 131.4 24.4 21.4 101.7 - 91.8 - 75.1 62.6 98.7 - 79.0 93.2 序号 1 2 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24
实用文档
25 26 27 Al2S3 Am Ar As (灰,gray) As(黄,yellow) As(黄,yellow) cr cr g cr cr g cr g l g l g g cr g cr cr cr cr g cr cr cr cr cr g l g l g g g g cr g cr g cr g cr cr cr cr cr -724.0 0.0 0.0 0.0 14.6 302.5 -197.5 -130.0 -305.0 -261.5 -821.3 -785.8 66.4 -58.2 - -924.9 -169.0 0.0 0.0 366.1 -53.3 -117.6 -363.6 0.0 0.0 565.0 -239.7 -205.6 -427.2 -1136.0 100.0 35.6 71.1 -1273.5 -843.8 -240.6 67.0 0.0 180.0 -757.3 -858.6 -1216.3 -1207.1 -178.7 - - - - - 261.0 - -159.0 -259.4 -248.9 -774.2 -770.8 68.9 -59.4 - -782.3 -168.6 - - 326.3 - - - - - 521.0 -238.5 -232.5 -387.4 -1119.4 - 86.7 20.7 -1194.3 -832.0 - - - 146.0 -736.8 -810.4 -1137.6 -1156.8 - - - 154.8 35.1 - 174.2 - 363.9 216.3 327.2 181.2 289.1 222.8 213.1 388.3 105.4 163.6 - 47.4 180.5 - - - - 5.9 153.4 229.7 324.2 206.3 254.4 - 232.1 349.2 54.0 279.8 - - 62.8 170.2 146.0 123.7 112.1 96.4 - - - 20.8 24.6 - 20.8 - 79.2 - 75.7 126.6 65.6 38.1 105.8 80.6 116.5 116.3 - 25.4 20.8 - - - - 11.1 20.8 - 67.8 106.7 50 - 56.9 70.8 - 66.9 - - 28.1 20.8 - 75.1 85.3 71.2 - 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56
AsBr3 AsCl3 AsF3 AsH3 AsI3 As2O5 As2S3 At Au AuBr3 AuCl3 AuF3 AuI B BBr3 BCl3 BF3 BH3 B2H6 BI3 B2O3 B2S3 Ba BaBr2 BaCl2 BaCO3 BaF2 BaH2 实用文档
57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 BaI2 Ba(NO2)2 Ba(NO3)2 BaO Ba(OH)2 BaS BaSO4 Be BeBr2 BeCl2 BeCO3 BeF2 BeI2 BeO Be(OH)2 BeS BeSO4 Bi BiCl3 BiI3 Bi(OH)3 Bi2O3 Bi2S3 Bk Br BrF3 BrF5 BrO CO CO2 Ca CaBr2 CaCl2 CaCO3 (方解石, calcite) CaCO3 (霰石, aragonite) cr cr cr cr cr cr cr cr g cr cr cr cr cr cr cr cr cr cr g cr g cr cr cr cr cr g l g l g g g g cr g cr cr cr -602.1 -768.2 -992.1 -553.5 -944.7 -460.0 -1473.2 0.0 324.0 -353.5 -490.4 -1025.0 -1026.8 -192.5 -609.4 -902.5 -234.3 -1205.2 0.0 207.1 -379.1 -265.7 - -711.3 -573.9 -143.1 0.0 111.9 -300.8 -255.6 -458.6 -428.9 125.8 -110.5 -393.5 0.0 177.8 -682.8 -795.4 -1207.6 - - -796.6 -525.1 - -456.0 -1362.2 - 286.6 - -445.6 - -979.4 - -580.1 -815.0 - -1093.8 - 168.2 -315.0 -256.0 -175.3 - -493.7 -140.6 - 82.4 -240.5 -229.4 -351.8 -350.6 108.2 -137.2 -394.4 - 144.0 -663.6 -748.8 -1129.1 - - 213.8 70.4 - 78.2 132.2 9.5 136.3 - 82.7 - 53.4 - 13.8 51.9 - 77.9 56.7 187.0 177.0 358.9 - - 151.5 200.4 - 175.0 178.2 292.5 225.1 320.2 237.6 197.7 213.8 41.6 154.9 130.0 108.4 91.7 - - 151.4 47.8 - 49.4 101.8 16.4 20.8 - 64.8 - 51.8 - - - - 85.7 25.5 20.8 105.0 79.7 - - 113.5 122.2 - 20.8 124.6 66.6 - 99.6 32.1 29.1 37.1 25.9 20.8 - 72.9 83.5 91 cr -1207.8 -1128.2 88.0 82.3
实用文档
92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120 121 122 123 124 125 126 127 128 129 130 CaF2 CaH2 CaI2 Ca(NO3)2 CaO Ca(OH)2 CaS CaSO4 Cd CdBr2 CdCl2 CdCO3 CdF2 CdI2 CdO Cd(OH)2 CdS CdSO4 Ce CeCl3 CeO2 CeS Cf Cl Cl2 Cl2CO ClF3 ClO2 Cl2OS Cl2O2S Cm Co CoBr2 CoCl2 CoCO3 CoF2 CoI2 Co(NO3)2 CoO cr cr cr cr cr cr cr cr cr g cr cr cr cr cr cr cr cr cr cr g cr cr cr cr g g g g l g g l g l cr cr g cr cr cr cr cr cr cr -1228.0 -181.5 -533.5 -938.2 -634.9 -985.2 -482.4 -1434.5 0.0 111.8 -316.2 -391.5 -750.6 -700.4 -203.3 -258.4 -560.7 -161.9 -933.3 0.0 423.0 -1053.5 -1088.7 -459.4 0.0 121.3 0.0 -219.1 -163.2 -189.5 102.5 -212.5 -245.6 -364.0 -394.1 0.0 0.0 424.7 -220.9 -312.5 -713.0 -692.0 -88.7 -420.5 -237.9 -1175.6 -142.5 -528.9 -742.8 -603.3 -897.5 -477.4 -1322.0 - - -296.3 -343.9 -669.4 -647.7 -201.4 -228.7 -473.6 -156.5 -822.7 - 385.0 -977.8 -1024.6 -451.5 - 105.3 - -204.9 -123.0 - 120.5 -198.3 - -320.0 - - - 380.3 - -269.8 - -647.2 - - -214.2 68.5 41.4 142.0 193.2 38.1 83.4 56.5 106.5 51.8 167.7 137.2 115.3 92.5 77.4 161.1 54.8 96.0 64.9 123.0 72.0 191.8 151.0 62.3 78.2 - 165.2 223.1 283.5 281.6 - 256.8 309.8 - 311.9 - - 30.0 179.5 - 109.2 - 82.0 - - 53.0 67.0 41.0 - 149.4 42.0 87.5 47.4 99.7 26.0 20.8 76.7 74.7 - - 80.0 43.4 - - 99.6 26.9 23.1 87.4 61.6 50.0 - 21.8 33.9 57.7 63.9 - 42.0 66.5 121.0 77.0 134.0 - 24.8 23.0 79.5 78.5 - 68.8 - - 55.2 实用文档
131 132 133 134 135 136 137 138 139 140 141 142 143 144 145 146 147 148 149 150 151 152 153 154 155 156 157 158 159 160 161 162 163 164 165 166 167 168 169 170 171 172 Co(OH)2 CoS CoSO4 Cr CrBr2 CrCl3 CrF3 CrI3 Cr2O3 Cs CsBr CsCl CsClO4 CsHCO3 Cs2CO3 CsF CsHSO4 CsI CsNH2 CsNO3 Cs2O2 CsOH Cs2O Cs2S Cs2SO3 Cs2SO4 Cu CuBr CuBr2 CuCl CuCl2 CuCN CuF2 CuI Cu(NO3)2 CuO Cu(OH)2 CuS CuSO4 CuWO4 Cu2O Cu2S cr cr cr cr g cr cr cr cr cr cr g cr cr cr cr cr cr cr cr cr cr cr cr cr cr cr cr cr g cr cr cr cr cr cr cr cr cr cr cr cr cr cr cr -539.7 -82.8 -888.3 0.0 396.6 -302.1 -556.5 -1159.0 -205.0 -1139.7 0.0 76.5 -405.8 -443.0 -443.1 -966.1 -1139.7 -553.5 -1158.1 -346.6 -118.4 -506.0 -286.2 -417.2 -345.8 -359.8 -1134.7 -1143.0 0.0 337.4 -104.6 -141.8 -137.2 -220.1 96.2 -542.7 -67.8 -302.9 -157.3 -449.8 -53.1 -771.4 -1105.0 -168.6 -79.5 -454.3 - -782.3 - 351.8 - -486.1 -1088.0 - -1058.1 - 49.6 -391.4 -414.5 -314.3 - -1054.3 -525.5 - -340.6 - -406.5 - - -308.1 - - -1323.6 - 297.7 -100.8 - -119.9 -175.7 111.3 - -69.5 - -129.7 - -53.6 -662.2 - -146.0 -86.2 79.0 - 118.0 23.8 174.5 - 123.0 93.9 - 81.2 85.2 175.6 113.1 101.2 175.1 - 204.5 92.8 - 123.1 - 155.2 - - 146.9 - - 211.9 33.2 166.4 96.1 - 86.2 108.1 84.5 - 96.7 - 42.6 - 66.5 109.2 - 93.1 120.9 - - - 23.4 20.8 - 91.8 78.7 - 118.7 32.2 20.8 52.9 52.5 108.3 - 123.9 51.1 - 52.8 - - - - 76.0 - - 134.9 24.4 20.8 54.7 - 48.5 71.9 - - 54.1 - 42.3 - 47.8 - - 63.6 76.3